Why is it not possible to make an image for this substance?

[digitalroll]

There is an SDF code for the substance:

 csChFnd80/10182207592D

 13 12  0  0  0  0  0  0  0  0999 V2000
   10.5699  -11.4468    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    9.8555  -11.0343    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    9.8555  -10.2093    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
    9.1410  -11.4468    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
   10.5699  -12.2717    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    8.4265  -11.0343    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0
    7.7121  -11.4468    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    7.7121  -12.2717    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.9976  -11.0343    0.0000 C   0  0  3  0  0  0  0  0  0  0  0  0
    6.2832  -11.4468    0.0000 S   0  0  3  0  0  0  0  0  0  0  0  0
    5.5687  -11.0343    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.9976  -10.2093    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0
    6.2832  -12.2717    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0
  1  2  1  0  0  0  0
  2  3  2  0  0  0  0
  2  4  1  0  0  0  0
  1  5  1  0  0  0  0
  4  6  1  4  0  0  0
  6  7  2  0  0  0  0
  7  8  1  0  0  0  0
  7  9  1  0  0  0  0
  9 10  1  0  0  0  0
 10 11  1  0  0  0  0
  9 12  1  0  0  0  0
 10 13  2  0  0  0  0
M  END

If I try to create an image for it using such a request:

{
  "data": {
    "type": "render",
    "attributes": {
      "compound": {
        "structure": "\n csChFnd80/10182207592D\n\n 13 12  0  0  0  0  0  0  0  0999 V2000\n   10.5699  -11.4468    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0\n    9.8555  -11.0343    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    9.8555  -10.2093    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n    9.1410  -11.4468    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n   10.5699  -12.2717    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    8.4265  -11.0343    0.0000 N   0  0  0  0  0  0  0  0  0  0  0  0\n    7.7121  -11.4468    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    7.7121  -12.2717    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    6.9976  -11.0343    0.0000 C   0  0  3  0  0  0  0  0  0  0  0  0\n    6.2832  -11.4468    0.0000 S   0  0  3  0  0  0  0  0  0  0  0  0\n    5.5687  -11.0343    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    6.9976  -10.2093    0.0000 C   0  0  0  0  0  0  0  0  0  0  0  0\n    6.2832  -12.2717    0.0000 O   0  0  0  0  0  0  0  0  0  0  0  0\n  1  2  1  0  0  0  0\n  2  3  2  0  0  0  0\n  2  4  1  0  0  0  0\n  1  5  1  0  0  0  0\n  4  6  1  4  0  0  0\n  6  7  2  0  0  0  0\n  7  8  1  0  0  0  0\n  7  9  1  0  0  0  0\n  9 10  1  0  0  0  0\n 10 11  1  0  0  0  0\n  9 12  1  0  0  0  0\n 10 13  2  0  0  0  0\nM  END\n",
        "format": "molfile"
      },
      "outputFormat": "image/png"
    }
  }
}

Then I get this error:

{
  "errors": [
    {
      "detail": "molfile loader: direction of bond #4 makes no sense"
    }
  ]
}

But if I open this substance in Ketcher, then I see the correct structure:

And I can even export an image of this substance:

Why does Indigo give an error? How to make the right image?

Indigo/Bingo version
1.7.0

[AATDev21]

There is a stereo-error in the molecule you used in the request, that why you got error message instead of an image. If you are sure anyway that this molecule is correct or this kind of errors are not important for you, they can be ignored with the option "ignore-stereochemistry-errors". Using of Indigo options in Indigo Service will be implemented soon in #1083.